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J Am Chem Soc. 2005 Sep 21;127(37):12776-7.

Synthesis and purification of a metallic nitride fullerene bisadduct: exploring the reactivity of Gd3N@C80.

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1
University of Southern Mississippi, Department of Chemistry and Biochemistry, 118 College Drive, #5043, Hattiesburg, Mississippi 39406, USA. Steven.Stevenson@usm.edu

Abstract

This research represents initial functionalization of a Gd3N@C80 metallic nitride fullerene (MNF). Results demonstrate that a bisadduct can be prepared in an isolable yield for this MRI precursor MNF. This Gd3N@C80 bisadduct is synthesized and purified, and preliminary characterization is reported. This is a significant finding as, to date, only MNF monoadducts have been purified.

PMID:
16159252
DOI:
10.1021/ja0535312
[Indexed for MEDLINE]
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