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Chem Commun (Camb). 2005 Sep 7;(33):4161-3. Epub 2005 Jul 22.

Simple iron-amine catalysts for the cross-coupling of aryl Grignards with alkyl halides bearing beta-hydrogens.

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1
School of Chemistry, University of Bristol, Cantock's Close, Bristol BS8 1TS, UK. r.bedford@bristol.ac.uk

Abstract

Mixtures of iron(III) chloride and appropriate amine ligands are active catalysts for the coupling of aryl Grignard reagents with primary and secondary alkyl halide substrates bearing beta-hydrogens, under mild and simple reaction conditions.

PMID:
16100589
DOI:
10.1039/b507133j
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