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J Am Chem Soc. 2005 Jul 27;127(29):10182-3.

Stable planar six-pi-electron six-membered N-heterocyclic carbenes with tunable electronic properties.

Author information

1
UCR-CNRS Joint Research Chemistry Laboratory (UMR 2282), Department of Chemistry, University of California, Riverside, California 92521-0403, USA.

Abstract

Carbene analogues of borazines are highly thermally stable. Keeping quasi-identical steric demands, the electronic properties of the carbene can be precisely tuned by varying the nature of the substituents at the boron centers.

PMID:
16028925
PMCID:
PMC2440681
DOI:
10.1021/ja052987g
[Indexed for MEDLINE]
Free PMC Article
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