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Org Lett. 2005 Jul 21;7(15):3327-9.

Microwave-enhanced aminocarbonylations in water.

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  • 1Organic Pharmaceutical Chemistry, Department of Medicinal Chemistry, Uppsala Biomedical Center, Uppsala University, Sweden.

Abstract

[reaction: see text]. Aryl bromides can be rapidly converted to the corresponding secondary and tertiary benzamides in water. By using Mo(CO)6 as the source of carbon monoxide, aminocarbonylations were conducted under air after only 10 min of high-density microwave heating.

PMID:
16018652
DOI:
10.1021/ol0512031
[PubMed]
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