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Nano Lett. 2005 Mar;5(3):451-5.

Chemical optimization of self-assembled carbon nanotube transistors.

Author information

  • 1Laboratoire d'Electronique Mol├ęculaire, CEA-DSM, CEA Saclay, 91191 Gif-sur-Yvette, France.

Abstract

We present the improvement of carbon nanotube field effects transistors (CNTFETs) performances by chemical tuning of the nanotube/substrate and nanotube/electrode interfaces. Our work is based on a method of selective placement of individual single walled carbon nanotubes (SWNTs) by patterned aminosilane monolayer and its use for the fabrication of self-assembled nanotube transistors. This method brings a relevant solution to the problem of systematic connection of self-organized nanotubes. The aminosilane monolayer reactivity can be used to improve carrier injection and doping level of the SWNT. We show that the Schottky barrier height at the nanotube/metal interface can be diminished in a continuous fashion down to an almost ohmic contact through these chemical treatments. Moreover, sensitivity to 20 ppb of triethylamine is demonstrated for self-assembled CNTFETs, thus opening new prospects for gas sensors taking advantages of the chemical functionality of the aminosilane used for assembling the CNTFETs.

PMID:
15755093
DOI:
10.1021/nl048032y
[PubMed - indexed for MEDLINE]
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