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Chem Commun (Camb). 2005 Feb 28;(8):1049-51. Epub 2005 Jan 10.

NO2 disproportionation for the IR characterisation of basic zeolites.

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1
Laboratoire Catalyse et Spectrochimir-UMR 6506-ENSICCaen, Caen, France.

Abstract

NO2 disproportionation on alkaline zeolites is used to generate nitrosonium (NO+) and nitrate ions on the surface, and the infrared vibrations observed are very sensitive to the cation chemical hardness and to the basicity of zeolitic oxygen atoms.

PMID:
15719112
DOI:
10.1039/b414664f

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