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Org Lett. 2005 Jan 20;7(2):263-6.

Selective organocatalytic oxygenation of hydrocarbons by dioxygen using anthraquinones and N-hydroxyphthalimide.

Author information

  • 1State Key Laboratory of Catalysis, Dalian Institute of Chemical Physics, Graduate School of the Chinese Academy of Sciences, Chinese Academy of Sciences, 457 Zhongshan Road, Dalian, 116023, PR China.

Abstract

[Reaction: see text] Purely organic and catalytic systems of anthraquinones and N-hydroxyphthalimide efficiently promote oxygenation of hydrocarbons with dioxygen under mild conditions, e.g., fluorene can be converted completely to fluorenone with 85% yield at 80 degrees C.

PMID:
15646973
DOI:
10.1021/ol047749p
[PubMed]
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