Extruding foams from corn starch acetate and native corn starch

Biomacromolecules. 2004 Nov-Dec;5(6):2329-39. doi: 10.1021/bm049512m.

Abstract

Because of the hydrophilic characteristics of native starch foams and the cost of modifying starch, the uses of starch and modified starch foams are hindered. To decrease hydrophilicity and cost of starch foams, native corn starch was blended with starch acetate and extruded. A twin-screw mixing extruder was used to produce the foams. Native starch content, screw speed, and barrel temperature had significant effects on molecular degradation of starches during extrusion. The melting temperature of extruded starch acetate/native starch foam was higher (216 degrees C) than that for starch acetate (193.4 degrees C). Strong peaks in the X-ray diffractograms of extruded starch acetate/native starch foam suggested new crystalline regions were formed. Optimum conditions for high radial expansion ratio, high compressibility, low specific mechanical energy requirement, and low water absorption index were 46.0% native starch content, 163 rpm screw speed, and 148 degrees C barrel temperature.

MeSH terms

  • Biocompatible Materials / chemistry*
  • Calorimetry, Differential Scanning
  • Crystallization
  • Macromolecular Substances
  • Regression Analysis
  • Spectrophotometry
  • Starch / analogs & derivatives*
  • Starch / chemistry*
  • Temperature
  • Water
  • X-Ray Diffraction
  • X-Rays
  • Zea mays

Substances

  • Biocompatible Materials
  • Macromolecular Substances
  • Water
  • Starch
  • starch acetate