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Langmuir. 2004 Nov 9;20(23):9889-92.

Immobilization and recovery of au nanoparticles from anion exchange resin: resin-bound nanoparticle matrix as a catalyst for the reduction of 4-nitrophenol.

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1
Department of Chemistry, Indian Institute of Technology, Kharagpur-721302, India.

Abstract

The immobilization of gold nanoparticles in anion exchange resin and their quantitative retrieval by means of a cationic surfactant, cetylpyridinium chloride, is studied. The resin-bound gold nanoparticles (R-Au) have been used successfully as a solid-phase catalyst for the reduction of 4-nitrophenol by sodium borohydride. At the end of the reaction, the solid matrix remains activated and separated from the product. The recycling of catalyst particles after the quantitative reduction of 4-nitrophenol and the recovery of gold nanoparticles with unaffected particle morphology from the resin-bound gold nanoparticle entity have been reported.

PMID:
15518467
DOI:
10.1021/la0486281

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