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J Org Chem. 2004 Oct 29;69(22):7779-82.

Ferrocenyl monophosphine ligands: synthesis and applications in the Suzuki-Miyaura coupling of aryl chlorides.

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1
Department of Chemistry, University of Liverpool, Liverpool L69 7ZD, UK.

Abstract

Ferrocenyl monophosphine ligands have been developed by a method based on palladium-catalyzed Suzuki-Miyaura coupling. The modular procedure creates a rapid synthesis of phosphines with diverse properties. The electron-rich phosphines have been successfully applied to the Suzuki-Miyaura coupling of activated and deactivated aryl chlorides, with low catalyst loading being feasible in the synthesis of tris-ortho-substituted biaryls.

PMID:
15498017
DOI:
10.1021/jo048963u
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