Recycling asymmetric hydrogenation catalysts by their immobilisation onto ion-exchange resins

Pierluigi Barbaro; Claudio Bianchini; Giuliano Giambastiani; Werner Oberhauser; Laura Morassi Bonzi; Filippo Rossi; Vladimiro Dal Santo

doi:10.1039/B406179A

Recycling asymmetric hydrogenation catalysts by their immobilisation onto ion-exchange resins

Dalton Trans. 2004 Jun 21:(12):1783-4. doi: 10.1039/B406179A. Epub 2004 May 19.

Authors

Pierluigi Barbaro¹, Claudio Bianchini, Giuliano Giambastiani, Werner Oberhauser, Laura Morassi Bonzi, Filippo Rossi, Vladimiro Dal Santo

Affiliation

¹ Istituto di Chimica dei Composti Organo Metallici, CNR, Area di Ricerca di Firenze, Via Madonna del Piano, 50019 Sesto Fiorentino, Firenze, Italy. pierluigi.barbaro@iccom.cnr.it

PMID: 15381978
DOI: 10.1039/B406179A

Abstract

New systems based on cationic chiral phosphine-rhodium complexes anchored to a commercial cation-exchange gel-type resin showed high efficiency and easy recycling in the asymmetric hydrogenation of prochiral olefins.