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Chem Commun (Camb). 2004 Aug 7;(15):1724-5. Epub 2004 Jun 28.

Lipase catalysed Michael addition of secondary amines to acrylonitrile.

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1
Departamento de Química Orgánica e Inorgánica, Universidad de Oviedo, C/Julián Claveria, 8, E-33071 Oviedo, Spain.

Abstract

A new enzymatic process is described. Different preparations of lipase B from Candida antarctica are able to catalyse Michael-type addition of secondary amines to acrylonitrile. This new reaction widens the applicability of these biocatalysts in organic synthesis.

PMID:
15278156
DOI:
10.1039/b402244k
[Indexed for MEDLINE]
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