Send to

Choose Destination
See comment in PubMed Commons below
J Chem Phys. 2004 Feb 15;120(7):3255-64.

Collision energy dependence of the HD(nu' = 2) product rotational distribution of the H + D2 reaction in the range 1.30-1.89 eV.

Author information

Department of Chemistry, Stanford University, Stanford, California 94305-5080, USA.


An experimental and theoretical investigation of the collision energy dependence of the HD(nu' = 2,j') rotational product state distribution for the H + D2 reaction in the collision energy range of Ecol = 1.30-1.89 eV has been carried out. Theoretical results based on time-dependent and time-independent quantum mechanical methods agree nearly perfectly with each other, and the agreement with the experiment is good at low collision energies and very good at high collision energies. This behavior is in marked contrast to a previous report on the HD(nu' = 3,j') product state rotational distribution [Pomerantz et al., J. Chem. Phys. 120, 3244 (2004)] where a systematic difference between experiment and theory was observed, especially at the highest collision energies. The reason for this different behavior is not yet understood. In addition, this study employs Doppler-free spectroscopy to resolve an ambiguity in the E, F-X resonantly enhanced multiphoton ionization transition originating from the HD(nu' = 2,j' = 1) state, which is found to be caused by an accidental blending with the transition coming from the HD(nu' = 1,j' = 14) state.

PubMed Commons home

PubMed Commons

How to join PubMed Commons

    Supplemental Content

    Full text links

    Icon for American Institute of Physics
    Loading ...
    Support Center