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Phys Rev Lett. 2004 May 28;92(21):215505. Epub 2004 May 28.

Exceptional ideal strength of carbon clathrates.

Author information

1
Laboratoire de Physique de la Matière Condensée et des Nanostructures, Université Claude Bernard Lyon I and CNRS, 43 Bd du 11 Novembre 1918, 69622 Villeurbanne Cedex, France. xblase@lpmcm.univ-lyon1.fr

Erratum in

  • Phys Rev Lett. 2004 Dec 3;93(23):239901.

Abstract

We study by means of ab initio calculations the ideal tensile and shear strengths of the C-46 clathrate phase. While its bulk modulus and elastic constants are smaller than in diamond, its strength is found to be in all directions larger than the critical stresses associated with the diamond [111] planes of easy slip. This can be related to the frustration by the clathrate cage structure of the diamond to graphite instability under nonhydrostatic stress conditions [corrected] The criteria for designing strong materials are discussed.

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