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J Am Chem Soc. 2004 Jun 2;126(21):6564-5.

Intramolecular reductive nitrosylation: reaction of nitric oxide and a copper(II) complex of a cyclam derivative with pendant luminescent chromophores.

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1
Department of Chemistry and Biochemistry, University of California - Santa Barbara, Santa Barbara, California 93106-9510, USA.

Abstract

The base-catalyzed reaction of nitric oxide with the Cu(II) complex Cu(DAC)2+ (DAC = 1,8-bis(9-anthracyl-methyl)-(1,4,8,11-tetraazacyclotetradecane)) leads to reduction of the metal center and the unexpected intramolecular nitrosylation of a secondary amine.

PMID:
15161279
DOI:
10.1021/ja049444b
[Indexed for MEDLINE]
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