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J Org Chem. 2004 Apr 16;69(8):2805-8.

Reactions of methylenecyclopropanes with phenylsulfenyl chloride and phenylselenyl chloride.

Author information

1
Department of Chemistry, East China Normal University, 3663 Zhong Shan Bei Lu, Shanghai 20062, China.

Abstract

The reaction of methylenecyclopropanes 1 with phenylsulfenyl chloride or phenylselenyl chloride gives (cyclobut-1-enylsulfanyl)benzene or (cyclobut-1-enylselanyl)benzene along with ring-opened product in good total yields at 0 degrees C in various solvents. A plausible mechanism has been proposed.

PMID:
15074931
DOI:
10.1021/jo049782v

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