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J Am Chem Soc. 2004 Mar 10;126(9):2668-9.

A bowl-shaped fullerene encapsulates a water into the cage.

Author information

1
Graduate School of Environmental Studies, Nagoya University, Nagoya 464-8601, Japan. iwmt@urban.env.nagoya-u.ac.jp

Abstract

The sequential carbon-carbon bond cleaving reactions of the diketone derivative of C60 with o-phenylenediamine give a novel bowl-shaped fullerene bearing a 20-membered ring orifice. The product reversibly encapsulates a water molecule into the fullerene cage for the first time.

PMID:
14995161
DOI:
10.1021/ja038537a
[Indexed for MEDLINE]

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