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Chem Commun (Camb). 2003 Nov 21;(22):2830-1.

Controlled crystallization of mixed-ligand complexes of 1,3-bis(4-pyridyl)propane-N,N'-dioxide with metal(II) thiocyanates: isostructurality in coordination networks bearing different mono- and di-nuclear nodes.

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1
Department of Chemistry, The Chinese University of Hong Kong, New Territories, Hong Kong, SAR, PR China.

Abstract

The new flexible spacer ligand 1,3-bis(4-pyridyl)propane-N,N'-dioxide forms three classes of isomorphous compounds with metal(iI) thiocyanates at controlled ligand-metal molar ratios, and its mu3-O,O,O' mode leads to a pair of coordination networks having the same (4, 4) topological characteristics but different mono- and di-nuclear nodes.

PMID:
14651126
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