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Chem Commun (Camb). 2003 Oct 7;(19):2438-9.

Rhodium-catalyzed Heck-type reaction of arylboronic acids with alpha,beta-unsaturated esters: tuning beta-hydrogen elimination vs. hydrolysis of alkylrhodium species.

Author information

1
Department of Chemistry, East China Normal University, 3663 North Zhongshan Rd., Shanghai, 200062, PR China. gzou@chem.ecnu.edu.cn

Abstract

The elusive rhodium-catalyzed Heck-type coupling of arylboronic acids with alpha,beta-unsaturated esters is effected using rhodium chloride as catalyst, indicating the hydrolysis of Rh-C bond could be finely tuned by the steric environment around rhodium.

PMID:
14587720
DOI:
10.1039/b305771m

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