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Chem Commun (Camb). 2003 Oct 7;(19):2408-9.

Metal-directed self-assembly of bimetallic dithiocarbamate transition metal cryptands and their binding capabilities.

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1
Department of Chemistry, Inorganic Chemistry Laboratory, University of Oxford, Oxford, UK OX1 3QR. paul.beer@chem.ox.ac.uk

Abstract

A novel family of redox-active dinuclear transition metal based cryptands self-assembled from dithiocarbamate ligands has been synthesised; depending upon the nature of the spacer groups these new cryptand systems have been shown to electrochemically recognise the binding of cations or anions.

PMID:
14587705
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