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Chem Commun (Camb). 2003 Sep 21;(18):2316-7.

Efficient, intermolecular, oxidative radical alkylation of heteroaromatic systems under "tin-free" conditions.

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1
Instituto de Química, Universidad Nacional Autónoma de México, Circuito Exterior S. N., Ciudad Universitaria, Coyoacán, México, DF 04510, México.

Abstract

Novel and efficient radical alkylation of several heterocyclic systems including pyrroles, indoles, furan and thiophenes is described using xanthate based radical chemistry. The present methodology could be used to provide rapid access to various nonsteroidal antiinflammatory drugs.

PMID:
14518892
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