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Chem Commun (Camb). 2003 Aug 7;(15):1928-9.

A zeolite-enzyme combination for biphasic dynamic kinetic resolution of benzylic alcohols.

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1
Centre for Surface Chemistry and Catalysis, KULeuven, Kasteelpark Arenberg 23, 3001 Leuven, Belgium.

Abstract

Acid zeolites like H-Beta are efficient heterogeneous catalysts for racemization of benzylic alcohols in water; by combination of the racemization with an enzymatic kinetic resolution in a two-phase system, enantiomerically pure esters were obtained in high yield via a dynamic kinetic resolution.

PMID:
12932037
[Indexed for MEDLINE]
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