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J Org Chem. 2003 Jun 27;68(13):5225-7.

Synthesis of allyl and alkyl vinyl ethers using an in situ prepared air-stable palladium catalyst. Efficient transfer vinylation of primary, secondary, and tertiary alcohols.

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  • 1Department of Chemistry and Biochemistry, Guelph-Waterloo Centre for Graduate Work in Chemistry (GWC)(2), University of Guelph, Guelph, Ontario, Canada N1G 2W1.

Abstract

An air-stable palladium catalyst formed in situ from commercially available components efficiently catalyzed the transfer vinylation between butyl vinyl ether and various allyl and alkyl alcohols to give the corresponding allyl and alkyl vinyl ethers in 61-98% yield in a single step.

PMID:
12816481
DOI:
10.1021/jo034376h
[PubMed]
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