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Nature. 2003 Jun 12;423(6941):705-14.

Reticular synthesis and the design of new materials.

Author information

1
Materials Design and Discovery Group, Department of Chemistry, 930 N. University Avenue, University of Michigan, Ann Arbor, Michigan 48109-1055, USA. oyaghi@umich.edu

Abstract

The long-standing challenge of designing and constructing new crystalline solid-state materials from molecular building blocks is just beginning to be addressed with success. A conceptual approach that requires the use of secondary building units to direct the assembly of ordered frameworks epitomizes this process: we call this approach reticular synthesis. This chemistry has yielded materials designed to have predetermined structures, compositions and properties. In particular, highly porous frameworks held together by strong metal-oxygen-carbon bonds and with exceptionally large surface area and capacity for gas storage have been prepared and their pore metrics systematically varied and functionalized.

PMID:
12802325
DOI:
10.1038/nature01650
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