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J Org Chem. 2003 May 2;68(9):3486-93.

Biosynthesis of Vitamin B(6) in yeast. Incorporation pattern of trioses.

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1
Department of Chemistry, McMaster University, Hamilton, Ontario, Canada L8S 4M1.

Abstract

The biosynthetic origin of the C(3) unit, C-6,5,5', of pyridoxamine was investigated in two yeasts, Candida utilis ATCC 9256 and Saccharomyces cerevisiae ATCC 7752. The incorporation patterns within pyridoxamine bishydrochloride derived from variously multiply (13)C- and (2)H-labeled samples of glycerol and glyceraldehyde, established by NMR spectroscopy, indicate that the three-carbon unit C-6,5,5' of pyridoxamine is derived intact from a triose.

PMID:
12713350
DOI:
10.1021/jo020730k
[Indexed for MEDLINE]
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