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Chem Commun (Camb). 2002 Dec 7;(23):2838-9.

A dynamic (reversible) covalent polymer: radical crossover behaviour of TEMPO-containing poly(alkoxyamine ester)s.

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1
Institute for Fundamental Research of Organic Chemistry, Kyushu University, Hakozaki, Higashi-ku, Fukuoka 812-858, Japan. otsuka@ms.ifoc.kyushu-u.ac.jp

Abstract

A dynamic covalent polymer incorporating thermally alkoxyamine units in the main chain was synthesized. Due to a radical crossover reaction between the alkoxyamine units, an interchange of the main chains in poly(alkoxyamine ester) was observed on heating.

PMID:
12478772
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