Abstract
The scope of solid-phase reactions utilizing a 'traceless' pi-arene-chromium linker has been expanded to include the addition of organo-lithium reagents to a supported ester group, generation and alkylation of an enolate anion, and substitution via the Mitsunobu reaction. Immobilization of ortho-disubstituted polyfunctionalized arene chromium dicarbonyl species onto the solid support and subsequent, selective transformation is also reported.
Publication types
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Research Support, U.S. Gov't, P.H.S.
MeSH terms
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Anions
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Benzene Derivatives / chemistry*
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Chromium / chemistry*
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Combinatorial Chemistry Techniques
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Cross-Linking Reagents / chemistry*
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Esters
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Lithium / chemistry
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Organometallic Compounds / chemistry*
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Polystyrenes / chemistry
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Styrene / chemistry
Substances
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Anions
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Benzene Derivatives
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Cross-Linking Reagents
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Esters
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Organometallic Compounds
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Polystyrenes
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Chromium
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Styrene
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Lithium