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Org Lett. 2002 May 30;4(11):1863-6.

In situ preparation of beta-D-1-O-hydroxylamino carbohydrate polymers mediated by galactose oxidase.

Author information

1
Department of Chemistry, Wayne State University, Detroit, Michigan 48202-3489, USA.

Abstract

[reaction: see text] Galactose oxidase produced a C-6 aldehyde in various terminal-containing galactose hydroxylamines for the simultaneous in situ generation of an A-B type condensation for the construction of unique oxime polymers. Molecular weights of the corresponding polymers were determined to be in the range of 4200-8900 g/mol, respectively. This indicates that approximately 20-25 sugar units were incorporated in these unique polymers.

PMID:
12027633
DOI:
10.1021/ol0258379
[Indexed for MEDLINE]

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