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J Am Chem Soc. 2002 May 29;124(21):5942-3.

[Au(2)Tl(2)(C(6)Cl(5))(4)].(CH(3))(2)C=O: a luminescent loosely bound butterfly cluster with a Tl(I)-Tl(I) interaction.

Author information

  • 1Departamento de Química Inorgánica-ICMA, Universidad de Zaragoza-CSIC, E-50009 Zaragoza, Spain.

Abstract

By reaction of NBu(4)[Au(C(6)Cl(5))(2)] with TlPF(6) in acetone the complex [Au(2)Tl(2)(C(6)Cl(5))(4)].(CH(3))(2)C=O is obtained, which shows a butterfly type arrangement of metals through short Au(I)-Tl(I) and Tl(I)-Tl(I) interactions. The last one is likely to be responsible for its luminescence behavior.

PMID:
12022818
[PubMed]
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