Format

Send to

Choose Destination
See comment in PubMed Commons below
Org Lett. 2002 May 16;4(10):1671-4.

Highly chemoselective rhodium-catalyzed methylenation of fluorine-containing ketones.

Author information

  • 1Département de Chimie, Université de Montréal, P.O. Box 6128, Station Downtown, Montréal, Québec, Canada H3C 3J7. lebelhe@chimie.umontreal.ca

Abstract

[reaction: see text] The rhodium(I)-catalyzed methylenation of functionalized fluorinated ketones using trimethylsilyldiazomethane proceeds to give the corresponding fluoromethylalkenes in good yields (61-90%). Remarkable chemoselectivity was observed for the synthesis of keto-substituted organofluorine alkenes.

PMID:
12000270
[PubMed - indexed for MEDLINE]
PubMed Commons home

PubMed Commons

0 comments
How to join PubMed Commons

    Supplemental Content

    Full text links

    Icon for American Chemical Society
    Loading ...
    Support Center