Reversing the stereoselectivity of the intermolecular Pauson-Khand reaction: formation of endo-fused norbornadiene adducts

Ramon Rios; Miquel A Pericàs; Albert Moyano; Miguel A Maestro; José Mahía

doi:10.1021/ol025649i

Reversing the stereoselectivity of the intermolecular Pauson-Khand reaction: formation of endo-fused norbornadiene adducts

Org Lett. 2002 Apr 4;4(7):1205-8. doi: 10.1021/ol025649i.

Authors

Ramon Rios¹, Miquel A Pericàs, Albert Moyano, Miguel A Maestro, José Mahía

Affiliation

¹ Unitat de Recerca en Síntesi Asimètrica, Departament de Química Orgànica, Facultat de Química, Universitat de Barcelona, Martí i Franquès, 1-11, 08028 Barcelona, Spain.

PMID: 11922819
DOI: 10.1021/ol025649i

Abstract

[reaction: see text] An unprecedented endo-selective and regioselective intermolecular Pauson-Khand reaction takes place when heterobimetallic (Mo-Co) complexes derived from N-(2-alkynoyl)oxazolidinones or sultams are heated in the presence of norbornadiene.