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Org Lett. 2002 Mar 7;4(5):749-52.

Stereoselective synthesis of vancosamine and saccharosamine glycals via tungsten-catalyzed alkynol cycloisomerization.

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  • 1Department of Chemistry, Emory University, 1515 Pierce Drive, Atlanta, Georgia 30322.

Abstract

[reaction: see text] A stereoselective synthesis of the C-3 branched amino glycals of vancosamine and saccharosamine is described that features a tungsten carbonyl catalyzed cycloisomerization of the corresponding alkynyl alcohol.

PMID:
11869118
[PubMed - indexed for MEDLINE]
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