Laboratory and in-situ reductions of soluble phosphorus in swine waste slurries

Environ Technol. 2001 Nov;22(11):1273-8. doi: 10.1080/09593332208618190.

Abstract

Laboratory and field experiments were conducted using magnesium chloride (MgCl2) to force the precipitation of struvite (MgNH4PO4 x 6H2O) and reduce the concentration of soluble phosphorus (SP) in swine waste. In laboratory experiments, reductions of SP of 76% (572 to 135 mg P l(-1)) were observed in raw swine manure after addition of magnesium chloride (MgCl2) at a rate calculated to provide a 1.6:1 molar ratio of magnesium (Mg) to total phosphorus. Adjusting the pH of the treated manure to pH 9.0 with sodium hydroxide (NaOH) increased SP reduction to 91% (572 to 50 mg P l(-1)). X-ray diffraction of the precipitate recovered from swine waste slurry treated only with MgCl2 confirmed the presence ofstruvite. The molar N:P:Mg ratio of the recovered precipitate was 1:1.95:0.24, suggesting that compounds in addition to struvite were formed. In a field experiment conducted in a swine manure holding pond, a 90% reduction in SP concentration was observed in approximately 140,000 l of swine manure slurry treated before land application with 2,000 l MgCl2 (64% solution) at ambient slurry temperatures ranging from 5 to 10 degrees C.

Publication types

  • Research Support, Non-U.S. Gov't

MeSH terms

  • Agriculture
  • Animals
  • Chemical Precipitation
  • Magnesium Chloride / chemistry
  • Magnesium Compounds / chemistry
  • Manure*
  • Phosphates / chemistry
  • Phosphorus / chemistry*
  • Refuse Disposal / methods*
  • Solubility
  • Struvite
  • Swine

Substances

  • Magnesium Compounds
  • Manure
  • Phosphates
  • Magnesium Chloride
  • Phosphorus
  • Struvite