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Org Lett. 2001 Dec 13;3(25):4111-3.

Efficient enantioselective hydrosilylation of ketones catalyzed by air stable copper fluoride-phosphine complexes.

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  • 1Laboratoire de Chimie Organique et M√©dicinale, Place Louis Pasteur, 1, Universit√© catholique de Louvain, B-1348 Louvain-La-Neuve, Belgium.

Abstract

[reaction: see text] Copper(II) fluoride-chiral diphosphine systems catalyze the hydrosilylation of several ketones with moderate to excellent enantioselectivities. An oxygen acceleration effect was observed and led to a practical protocol with low catalyst loading.

PMID:
11735597
[PubMed]
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