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J Org Chem. 1998 Sep 4;63(18):6344-6347.

Short Enantioselective Total Syntheses of the Piperidine Alkaloids (S)-Coniine and (2R,6R)-trans-Solenopsin A via Catalytic Asymmetric Imine Hydrosilylation.

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1
Massachusetts Institute of Technology, Cambridge, Massachusetts 02139.

Abstract

The enantioselective syntheses of (S)-coniine and (2R,6R)-trans-solenopsin A are reported. The key step in both syntheses is the catalytic asymmetric hydrosilylation of a cyclic imine.

PMID:
11672268
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