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Bis(μ-2-fluoro-benzoato-1:2κO:O')(2-fluoro-benzoato-1κO,O')(2-fluoro-benzoato-2κO)dinicotinamide-1κN,2κN-dizinc(II)-2-fluoro-benzoic acid (1/1).
Hökelek T, Yılmaz F, Tercan B, Ozbek FE, Necefoğlu H. Hökelek T, et al. Acta Crystallogr Sect E Struct Rep Online. 2009 Nov 21;65(Pt 12):m1608-9. doi: 10.1107/S1600536809048089. Acta Crystallogr Sect E Struct Rep Online. 2009. PMID: 21578633 Free PMC article.
Within the binuclear mol-ecule, the pyridine rings are oriented at a dihedral angle of 19.41 (14). In the crystal structure, the uncoordinated 2-fluorobenzoic acid mol-ecules are linked by O-HO hydrogen bonding, forming centrosymmetric supra-molecular dimers. …
Within the binuclear mol-ecule, the pyridine rings are oriented at a dihedral angle of 19.41 (14). In the crystal structure, the uncoordinat …
Effects of the matrix and intramolecular interactions on the stability of the higher-energy conformers of 2-fluorobenzoic acid.
Kuş N, Fausto R. Kuş N, et al. J Chem Phys. 2017 Mar 28;146(12):124305. doi: 10.1063/1.4978794. J Chem Phys. 2017. PMID: 28388141
DFT(B3LYP)/6-311++G(d,p) calculations on 2-fluorobenzoic acid (2FBA) show that the molecule has four conformers: two low energy conformers (forms I and II) with the carboxylic acid group assuming the cis configuration (O=C-O-H dihedral equal to 0) and two hig …
DFT(B3LYP)/6-311++G(d,p) calculations on 2-fluorobenzoic acid (2FBA) show that the molecule has four conformers: two lo …
Tetrahydroacridine derivatives with fluorobenzoic acid moiety as multifunctional agents for Alzheimer's disease treatment.
Czarnecka K, Szymański P, Girek M, Mikiciuk-Olasik E, Skibiński R, Kabziński J, Majsterek I, Malawska B, Jończyk J, Bajda M. Czarnecka K, et al. Bioorg Chem. 2017 Jun;72:315-322. doi: 10.1016/j.bioorg.2017.05.003. Epub 2017 May 5. Bioorg Chem. 2017. PMID: 28501648
A novel series of 9-amino-1,2,3,4-tetrahydroacridine derivatives with 2-fluorobenzoic acid or 3-fluorobenzoic acid moiety were designed, synthesized and evaluated as inhibitors of cholinesterases and aggregation of beta-amyloid. ...
A novel series of 9-amino-1,2,3,4-tetrahydroacridine derivatives with 2-fluorobenzoic acid or 3-fluorobenzoic acid moie …
Fluoro-Bridged Clusters in Rare-Earth Metal-Organic Frameworks.
Vizuet JP, Mortensen ML, Lewis AL, Wunch MA, Firouzi HR, McCandless GT, Balkus KJ Jr. Vizuet JP, et al. J Am Chem Soc. 2021 Nov 3;143(43):17995-18000. doi: 10.1021/jacs.1c10493. Epub 2021 Oct 22. J Am Chem Soc. 2021. PMID: 34677056
The modulator 2-fluorobenzoic acid (2-fba) is widely used to prepare RE clusters in metal-organic frameworks (MOFs). ...
The modulator 2-fluorobenzoic acid (2-fba) is widely used to prepare RE clusters in metal-organic frameworks (MOFs). .. …
Carboxyl position-directed structure diversity in zirconium-tricarboxylate frameworks.
Xia J, Si J, Zhou K, Xia HL, Zhang J, Xu Y, Wang L, Liu XY. Xia J, et al. Dalton Trans. 2023 Dec 5;52(47):17679-17683. doi: 10.1039/d3dt03348a. Dalton Trans. 2023. PMID: 37997636
Nanosized HIAM-4033 exhibits excellent sensitivity and selectivity for detecting aromatic acids, such as benzoic acid and 2-fluorobenzoic acid, compared with aliphatic acids and inorganic acids. ...
Nanosized HIAM-4033 exhibits excellent sensitivity and selectivity for detecting aromatic acids, such as benzoic acid and 2-fluoro
Fluorine extraction from organofluorine molecules to make fluorinated clusters in yttrium MOFs.
Abbas M, Maceda AM, Firouzi HR, Xiao Z, Arman HD, Shi Y, Zhou HC, Balkus KJ Jr. Abbas M, et al. Chem Sci. 2022 Nov 26;13(48):14285-14291. doi: 10.1039/d2sc05143e. eCollection 2022 Dec 14. Chem Sci. 2022. PMID: 36545134 Free PMC article.
Yttrium dimer nodes are formed in the absence of a modulator, resulting in a 2D layered coordination network (Y-BCA-2D). The presence of fluorinating agents, e.g., 2-fluorobenzoic acid (2-FBA), 2,6-difluorobenzoic acid (2,6-DFBA), and perfluorohexanoic acid ( …
Yttrium dimer nodes are formed in the absence of a modulator, resulting in a 2D layered coordination network (Y-BCA-2D). The presence of flu …
Carbon 14 synthesis of glycine transporter 1 inhibitor Iclepertin (BI 425809) and its major metabolites.
Latli B, Hrapchak MJ, Frutos RP, Lee H, Song JJ. Latli B, et al. J Labelled Comp Radiopharm. 2023 Sep;66(11):336-344. doi: 10.1002/jlcr.4051. Epub 2023 Jun 29. J Labelled Comp Radiopharm. 2023. PMID: 37382087
Iclepertin is composed of two main chemical blocks, (R)-5-(methylsulfonyl)-2-([1,1,1-trifluoropropan-2-yl]oxy)benzoic acid (2), and 3-[(1R,5R)-3-azabicyclo[3.1.0]hexan-5-yl]-5-(trifluoromethyl)isoxazole (3) linked to each other via an amide bond. In the first synthesis of carbon …
Iclepertin is composed of two main chemical blocks, (R)-5-(methylsulfonyl)-2-([1,1,1-trifluoropropan-2-yl]oxy)benzoic acid (2), and 3-[(1R,5 …
A Eu(iii) metal-organic framework based on anthracenyl and alkynyl conjugation as a fluorescence probe for the selective monitoring of Fe3+ and TNP.
Zhao Y, Wang CA, Li JK, Li QL, Guo Q, Ru J, Ma CL, Han YF. Zhao Y, et al. RSC Adv. 2022 Sep 21;12(41):26945-26952. doi: 10.1039/d2ra02892a. eCollection 2022 Sep 16. RSC Adv. 2022. PMID: 36320831 Free PMC article.
The MOF exhibits a stable UiO-66 crystal structure, and a six-core cluster twelve-linked secondary structural unit was successfully synthesized using 2-fluorobenzoic acid as a modulator, forming a classical fcu topology. ...
The MOF exhibits a stable UiO-66 crystal structure, and a six-core cluster twelve-linked secondary structural unit was successfully synthesi …
47 results