Multihydroxy-Anthraquinone Derivatives as Free Radical and Cationic Photoinitiators of Various Photopolymerizations under Green LED.
Macromol Rapid Commun. 2018.
PMID: 29676024
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Carbazole-based compounds as photoinitiators for free radical and cationic polymerization upon near visible light illumination.
Photochem Photobiol Sci. 2018.
PMID: 29620093
Search results
Page 1
Free-Radical Photopolymerization for Curing Products for Refinish Coatings Market.
Polymers (Basel). 2022 Jul 13;14(14):2856. doi: 10.3390/polym14142856.
Polymers (Basel). 2022.
PMID: 35890631
Free PMC article.
Review.
Even though there are many photocurable compositions that are cured by cationic photopolymerization mechanisms, UV curing generally consists of the formation of cross-linking covalent bonds between a resin and monomers via a photoinitiated free radical …
Even though there are many photocurable compositions that are cured by cationic photopolymerization mechanisms, UV curing generally c …
Lawsone Derivatives as Efficient Photopolymerizable Initiators for Free-Radical, Cationic Photopolymerizations, and Thiol-Ene Reactions.
Polymers (Basel). 2021 Jun 20;13(12):2015. doi: 10.3390/polym13122015.
Polymers (Basel). 2021.
PMID: 34203069
Free PMC article.
Two new photopolymerizable vinyl (2-(allyloxy) 1,4-naphthoquinone, HNQA) and epoxy (2-(oxiran-2yl methoxy) 1,4-naphthoquinone, HNQE) photoinitiators derived from lawsone were designed in this paper. These new photoinitiators can be used as one-component photoinit …
Two new photopolymerizable vinyl (2-(allyloxy) 1,4-naphthoquinone, HNQA) and epoxy (2-(oxiran-2yl methoxy) 1,4-naphthoquinone, HNQE) phot …
Chemiluminescence-Induced Free Radical-Promoted Cationic Polymerization.
Macromol Rapid Commun. 2020 Apr;41(8):e2000004. doi: 10.1002/marc.202000004. Epub 2020 Feb 26.
Macromol Rapid Commun. 2020.
PMID: 32100902
Chemiluminescence (CL) has recently been featured as a new external light source for various photoinduced reactions with attractive features such as eliminating continuous energy supply and advanced light source setups. In the present study, the free-radical-promote …
Chemiluminescence (CL) has recently been featured as a new external light source for various photoinduced reactions with attractive features …
Carbazole-based compounds as photoinitiators for free radical and cationic polymerization upon near visible light illumination.
Photochem Photobiol Sci. 2018 May 16;17(5):578-585. doi: 10.1039/c7pp00400a.
Photochem Photobiol Sci. 2018.
PMID: 29620093
Six new carbazole based compounds (Ca1-Ca6) are synthesized and proposed as high performance photoinitiators with iodonium salt (iod) and/or an amine (EDB) for both the free radical polymerization (FRP) of acrylates and the cationic polymerization (CP) …
Six new carbazole based compounds (Ca1-Ca6) are synthesized and proposed as high performance photoinitiators with iodonium salt (iod) …
Phenacyl Phenothiazinium Salt as a New Broad-Wavelength-Absorbing Photoinitiator for Cationic and Free Radical Polymerizations.
Angew Chem Int Ed Engl. 2021 Jul 26;60(31):16917-16921. doi: 10.1002/anie.202104531. Epub 2021 Jun 24.
Angew Chem Int Ed Engl. 2021.
PMID: 34048634
Photophysical, photochemical, and computational investigations revealed that P-PTh in solution decomposes at all wavelengths by homolytic and heterolytic cleavages and generates cationic and radical species, which could efficiently initiate cationic and fr …
Photophysical, photochemical, and computational investigations revealed that P-PTh in solution decomposes at all wavelengths by homolytic an …
Water-Soluble Photoinitiators in Biomedical Applications.
Polymers (Basel). 2020 May 7;12(5):1073. doi: 10.3390/polym12051073.
Polymers (Basel). 2020.
PMID: 32392892
Free PMC article.
Review.
The division of initiators according to the method of photoinitiation was described and the related mechanisms were discussed. Examples from each group of photoinitiators are presented, and their benefits, limitations, and applications are outlined....
The division of initiators according to the method of photoinitiation was described and the related mechanisms were discussed. Exampl …
Towards new NIR dyes for free radical photopolymerization processes.
Beilstein J Org Chem. 2021 Aug 16;17:2067-2076. doi: 10.3762/bjoc.17.133. eCollection 2021.
Beilstein J Org Chem. 2021.
PMID: 34476013
Free PMC article.
Markedly, noncharged structures, negatively charged cyanine bearing Na(+) as counter cation, and positively charged cyanines bearing (B(Ph)(4) (-)) or (I(-)) as counter anions were examined as promising NIR light photoinitiating systems. Excellent photoinitiating …
Markedly, noncharged structures, negatively charged cyanine bearing Na(+) as counter cation, and positively charged cyanines bearing …
N-Vinylcarbazole: An Additive for Free Radical Promoted Cationic Polymerization upon Visible Light.
ACS Macro Lett. 2012 Jul 17;1(7):802-806. doi: 10.1021/mz3002325. Epub 2012 Jun 11.
ACS Macro Lett. 2012.
PMID: 35607121
The generated radicals can be further easily oxidized by an iodonium salt thereby leading to efficient initiating cations for the ROP of epoxides. Different visible light photoinitiating systems have been investigated: Type I photoinitiators (derived f …
The generated radicals can be further easily oxidized by an iodonium salt thereby leading to efficient initiating cations for …
A New Phosphine for Efficient Free Radical Polymerization under Air.
Macromol Rapid Commun. 2020 May;41(9):e2000053. doi: 10.1002/marc.202000053. Epub 2020 Mar 20.
Macromol Rapid Commun. 2020.
PMID: 32196131
A new phosphine is proposed as efficient coinitiator for camphorquinone (CQ)-based photoinitiating systems for the free radical polymerization of (meth)acrylates. Remarkably, this new co-initiator can exhibit two functionalities: a phosphine moiety to overcom …
A new phosphine is proposed as efficient coinitiator for camphorquinone (CQ)-based photoinitiating systems for the free rad …
Multihydroxy-Anthraquinone Derivatives as Free Radical and Cationic Photoinitiators of Various Photopolymerizations under Green LED.
Macromol Rapid Commun. 2018 Oct;39(19):e1800172. doi: 10.1002/marc.201800172. Epub 2018 Apr 20.
Macromol Rapid Commun. 2018.
PMID: 29676024
Furthermore, the multihydroxy-anthraquinone derivative-based photoinitiating systems are capable of initiating cationic photopolymerization of epoxides or divinyl ethers under green LED, and the relevant photoinitiation ability is consistent with the photoche …
Furthermore, the multihydroxy-anthraquinone derivative-based photoinitiating systems are capable of initiating cationic photop …
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