Removal of Congo red dyes from aqueous solutions by porous γ-alumina nanoshells

Porous alumina has been shown to be an excellent adsorbent for Congo Red (CR) dye. In this work, highly porous g-Al₂O₃ nanoshells were synthesized from alumina coated carbon black (CB) obtained from a new deposition technique and used for removal of CR dye from aqueous solutions. Adsorption experiments were conducted in a batch mode and a series of parameters were investigated, including contact time, initial dye concentrations, ionic strength and pH of the solutions. It was found that equilibrium for CR adsorption can be reached within 30 min, much faster than reported by other studies in the literature on similar adsorbents. It was also found that the adsorption capacity of Al₂O₃ nanoshells is 44.8 % higher than that of alumina/CB. The adsorption capacity of Al₂O₃ nanoshells was more favorable at lower pH, and the optimal adsorption ability was achieved at pH 4.0 with a removal efficiency at 98.6 %. The Al₂O₃ nanoshells have a maximum adsorption capacity of 370.4 mg g^-1 (25 °C; pH 7; no salt added), better than or comparable to those reported in the literature. A pseudo-second-order kinetics model can best fit the kinetics of CR adsorption, which follows the Langmuir isotherm. The high adsorption capacity is attributed to the strong hydrogen-bonding interactions between the anionic dye and Al₂O₃ nanoshells surface as well as to the electrostatic interactions between CR dye and the Al₂O₃ nanoshells.