Composite Hybrid Cluster Built from the Integration of Polyoxometalate and a Metal Halide Cluster: Synthetic Strategy, Structure, and Properties

Xin-Xiong Li; Xiang Ma; Wen-Xu Zheng; Yan-Jie Qi; Shou-Tian Zheng; Guo-Yu Yang

doi:10.1021/acs.inorgchem.6b01453

Composite Hybrid Cluster Built from the Integration of Polyoxometalate and a Metal Halide Cluster: Synthetic Strategy, Structure, and Properties

Inorg Chem. 2016 Sep 6;55(17):8257-9. doi: 10.1021/acs.inorgchem.6b01453. Epub 2016 Aug 11.

Authors

Xin-Xiong Li¹, Xiang Ma¹, Wen-Xu Zheng¹, Yan-Jie Qi¹, Shou-Tian Zheng¹, Guo-Yu Yang²

Affiliations

¹ State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University , Fuzhou, Fujian 350108, China.
² MOE Key Laboratory of Cluster Science, School of Chemistry, Beijing Institute of Technology , Beijing 100081, China.

PMID: 27513868
DOI: 10.1021/acs.inorgchem.6b01453

Abstract

A step-by-step synthetic strategy, setting up a bridge between the polyoxometalate (POM) and metal halide cluster (MHC) systems, is demonstrated to construct an unprecedented composite hybrid cluster built up from one high-nuclearity cationic MHC [Cu8I6](2+) and eight Anderson-type anionic POMs [HCrMo6O18(OH)6](2-) cross-linked by a tripodal alcohol derivative.