Retention Behavior of Halogenated Benzenes on a Stationary Phase Having a 2,4-Dibromophenoxy Group as the Halogen Recognition Functional Group

Toshio Miwa; Shiho Suzuki; Rina Takai; Ryohei Yamamoto; Yoshinori Inoue; Atsushi Yamamoto

doi:10.2116/analsci.31.841

Retention Behavior of Halogenated Benzenes on a Stationary Phase Having a 2,4-Dibromophenoxy Group as the Halogen Recognition Functional Group

Anal Sci. 2015;31(8):841-5. doi: 10.2116/analsci.31.841.

Authors

Toshio Miwa¹, Shiho Suzuki, Rina Takai, Ryohei Yamamoto, Yoshinori Inoue, Atsushi Yamamoto

Affiliation

¹ College of Bioscience and Biotechnology, Chubu University.

PMID: 26256610
DOI: 10.2116/analsci.31.841

Abstract

A stationary phase with a dipole interaction was synthesized by immobilizing the 2,4-dibromophenoxy (DBP) group onto a hydrophilic base resin. The chromatographic properties for halogenated benzenes were evaluated on the DBP-resin by reversed phase mode. The separation efficiency of the DBP-resin for p-xylene and 1,4-dihalogenated benzenes was better than that of the column packed with octadecylsilane (ODS). The results suggested that the retention of the solutes on the DBP-resin depends on the Debye interaction in addition to with the dispersion force caused by the DBP group.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Benzene / chemistry*
Benzene / isolation & purification*
Chromatography, Liquid / methods*
Halogenation*
Pentanones / chemistry*
Silanes / chemistry
Silicon Dioxide / chemistry

Substances

Pentanones
Silanes
dibenzoylpropane
octadecylsilane
Silicon Dioxide
Benzene