Tandem catalysis with a bifunctional site-isolated Lewis acid-Brønsted base metal-organic framework, NH2-MIL-101(Al)

Renganathan Srirambalaji; Soonsang Hong; Ramalingam Natarajan; Minyoung Yoon; Raghunandan Hota; Yonghwi Kim; Young Ho Ko; Kimoon Kim

doi:10.1039/c2cc36678a

Tandem catalysis with a bifunctional site-isolated Lewis acid-Brønsted base metal-organic framework, NH2-MIL-101(Al)

Chem Commun (Camb). 2012 Dec 11;48(95):11650-2. doi: 10.1039/c2cc36678a.

Authors

Renganathan Srirambalaji¹, Soonsang Hong, Ramalingam Natarajan, Minyoung Yoon, Raghunandan Hota, Yonghwi Kim, Young Ho Ko, Kimoon Kim

Affiliation

¹ Center for Smart Supramolecules, Department of Chemistry, Pohang University of Science and Technology, Republic of Korea.

PMID: 23104231
DOI: 10.1039/c2cc36678a

Abstract

A metal-organic framework (MOF), NH(2)-MIL-101(Al), which acts as a bifunctional, site-isolated Lewis acid-Brønsted base heterogeneous catalyst, catalyzes a tandem Meinwald rearrangement-Knoevenagel condensation reaction with remarkable substrate selectivity.

Publication types

Research Support, Non-U.S. Gov't

MeSH terms

Aldehydes / chemistry
Catalysis
Epoxy Compounds / chemistry
Lewis Acids / chemistry*
Lewis Bases / chemistry*
Metals / chemistry*
Organometallic Compounds / chemistry*

Substances

Aldehydes
Epoxy Compounds
Lewis Acids
Lewis Bases
Metals
Organometallic Compounds