Novel incineration technology integrated with drying, pyrolysis, gasification, and combustion of MSW and ashes vitrification

Environ Sci Technol. 2005 May 15;39(10):3855-63. doi: 10.1021/es040408m.

Abstract

The conventional mass burn systems for municipal solid waste (MSW) emit large amount of acidic gases and dioxins as well as heavy metals due to the large excess air ratio. Additionally, the final process residues, bottom ash with potential leachability of heavy metals and fly ash with high level of heavy metals and dioxins, also constitute a major environmental problem. To deal with these issues more effectively, a novel MSW incineration technology was developed in this study. MSW drying, pyrolysis, gasification, incineration, and ash vitrification were achieved as a spectrum of combustion by the same equipment (primary chamber) in one step. In practice, the primary chamber of this technology actually acted as both gasifier for organic matter and vitrifying reactor for ashes, and the combustion process was mainly completed in the secondary chamber. Experiments were carried outto examine its characteristics in an industrial MSW incineration plant, located in Taiyuan, with a capability of 100 tons per day (TPD). Results showed that (1) the pyrolysis, gasification, and vitrification processes in the primary chamber presented good behaviors resulting in effluent gases with high contents of combustibles (e.g., CO and CH4) and bottom ash with a low loss-on-ignition (L.o.l), low leachability of heavy metals, and low toxicity of cyanide and fluoride. The vitrified bottom ash was benign to its environment and required no further processing for its potential applications. (2) Low stack emissions of dioxins (0.076 ng of TEQ m(-3)), heavy metals (ranging from 0.013 to 0.033 mg m(-3)), and other air pollutants were achieved. This new technology could effectively dispose Chinese MSW with a low calorific value and high water content; additionally, it also had a low capital and operating costs compared with the imported systems.

MeSH terms

  • Air Pollutants / analysis*
  • Air Pollution / prevention & control*
  • Benzofurans / analysis
  • Carbon
  • Carbon Monoxide / analysis
  • China
  • Coal Ash
  • Desiccation
  • Dibenzofurans, Polychlorinated
  • Glass
  • Hydrochloric Acid / analysis
  • Hydrofluoric Acid / analysis
  • Incineration / economics
  • Incineration / instrumentation
  • Incineration / methods*
  • Metals, Heavy / analysis
  • Nitrogen Oxides / analysis
  • Particulate Matter
  • Polychlorinated Dibenzodioxins / analogs & derivatives
  • Polychlorinated Dibenzodioxins / analysis
  • Sulfur Dioxide / analysis

Substances

  • Air Pollutants
  • Benzofurans
  • Coal Ash
  • Dibenzofurans, Polychlorinated
  • Metals, Heavy
  • Nitrogen Oxides
  • Particulate Matter
  • Polychlorinated Dibenzodioxins
  • Sulfur Dioxide
  • Carbon
  • Carbon Monoxide
  • Hydrochloric Acid
  • Hydrofluoric Acid