Nb and Mn Co-Modified Na0.5Bi4.5Ti4O15 Bismuth-Layered Ceramics for High-Frequency Transducer Applications

Micromachines (Basel). 2022 Aug 2;13(8):1246. doi: 10.3390/mi13081246.

Abstract

Lead-free environmentally friendly piezoelectrical materials with enhanced piezoelectric properties are of great significance for high-resolution ultrasound imaging applications. In this paper, Na0.5Bi4.5Ti3.86Mn0.06Nb0.08O15+y (NBT-Nb-Mn) bismuth-layer-structured ceramics were prepared by solid-phase synthesis. The crystallographic structure, micromorphology, and piezoelectrical and electromechanical properties of NBT-Nb-Mn ceramics were examined, showing their enhanced piezoelectricity (d33 = 33 pC/N) and relatively high electromechanical coupling coefficient (kt = 0.4). The purpose of this article is to describe the development of single element ultrasonic transducers based on these piezoelectric ceramics. The as-prepared high-frequency tightly focused transducer (ƒ-number = 1.13) had an electromechanical coupling coefficient of 0.48. The center frequency was determined to be 37.4 MHz and the -6 dB bandwidth to be 47.2%. According to the B-mode imaging experiment of 25 μm tungsten wires, lateral resolution of the transducer was calculated as 56 μm. Additionally, the experimental results were highly correlated to the results simulated by COMSOL software. By scanning a coin, the imaging effect of the transducer was further evaluated, demonstrating the application advantages of the prepared transducer in the field of high-sensitivity ultrasound imaging.

Keywords: environmental friendliness; high-resolution imaging; ultrasound imaging; ultrasound transducers.

Grants and funding

This work was supported by the National Science Foundation of China (Grant No. 52102128), the Natural Science Foundation of Hubei Province of China (Grant No. 2021CFB117), and the Open Project Fund of Hubei Key Laboratory of Ferro & Piezoelectric Materials and Devices (Grant Nos. K202010 and K202102). We acknowledge the support of the Xijiang Innovation Team Introduction Program of Zhaoqing (Jiecheng).