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A dual-function liquid electrolyte additive for high-energy non-aqueous lithium metal batteries.
Zhang Y, Wu Y, Li H, Chen J, Lei D, Wang C. Zhang Y, et al. Nat Commun. 2022 Mar 11;13(1):1297. doi: 10.1038/s41467-022-28959-5. Nat Commun. 2022. PMID: 35277497 Free PMC article.
Engineering the formulation of non-aqueous liquid electrolytes is a viable strategy to produce high-energy lithium metal batteries. However, when the lithium metal anode is combined with a Ni-rich layered cathode, the (electro)chemical stability of both electrodes c …
Engineering the formulation of non-aqueous liquid electrolytes is a viable strategy to produce high-energy lithium metal batteries. H …
Directional Ion Transport Enabled by Self-Luminous Framework for High-Performance Quasi-Solid-State Lithium Metal Batteries.
Ye S, Tian F, Shi K, Lei D, Wang C. Ye S, et al. Adv Sci (Weinh). 2023 Feb;10(4):e2205108. doi: 10.1002/advs.202205108. Epub 2022 Dec 11. Adv Sci (Weinh). 2023. PMID: 36507601 Free PMC article.
Composite gel polymer electrolyte (CGPE), derived from ceramic fillers has emerged as one of the most promising candidates to improve the safety and cycling stability of lithium metal batteries. However, the poor interface compatibility between the ceramic phase and polyme …
Composite gel polymer electrolyte (CGPE), derived from ceramic fillers has emerged as one of the most promising candidates to improve the sa …
Solvation Sheath Engineering by Multivalent Cations Enabling Multifunctional SEI for Fast-Charging Lithium-Metal Batteries.
Liu L, Zhao W, Zhang M, Fan Z, Liu Y, Pan Z, Zhao X, Yang X. Liu L, et al. ACS Appl Mater Interfaces. 2023 Nov 29. doi: 10.1021/acsami.3c13306. Online ahead of print. ACS Appl Mater Interfaces. 2023. PMID: 38029370
With the pursuit of high energy and power density, the fast-charging capability of lithium-metal batteries has progressively been the primary focus of attention. ...Consequently, our approach facilitated the deposition of lithium metal in a uniform and chunky way, e …
With the pursuit of high energy and power density, the fast-charging capability of lithium-metal batteries has progressively been the …
The determination of trace free acid content in lithium-ion battery electrolytes by coulometric titration in non-aqueous media.
Huang C, Shen C, Jin L, Qu D, Hu X, Lin Y, Cai H. Huang C, et al. Analyst. 2020 Jan 21;145(2):582-587. doi: 10.1039/c9an01539f. Epub 2019 Nov 26. Analyst. 2020. PMID: 31769453
The free acid in lithium-ion battery electrolytes was directly titrated with ethoxide ions generated through the electrolyzation of a 0.50 mol L(-1) LiCl ethanol solution. ...Thus, this study provides a simple, fast and accurate analytical method with a lower detect …
The free acid in lithium-ion battery electrolytes was directly titrated with ethoxide ions generated through the electrolyzati …
Atomic Layer Deposition of Lithium Niobium Oxides as Potential Solid-State Electrolytes for Lithium-Ion Batteries.
Wang B, Zhao Y, Banis MN, Sun Q, Adair KR, Li R, Sham TK, Sun X. Wang B, et al. ACS Appl Mater Interfaces. 2018 Jan 17;10(2):1654-1661. doi: 10.1021/acsami.7b13467. Epub 2018 Jan 5. ACS Appl Mater Interfaces. 2018. PMID: 29219291
The development of solid-state electrolytes by atomic layer deposition (ALD) holds unparalleled advantages toward the fabrication of next-generation solid-state batteries. Lithium niobium oxide (LNO) thin films with well-controlled film thickness and composition were succe …
The development of solid-state electrolytes by atomic layer deposition (ALD) holds unparalleled advantages toward the fabrication of next-ge …
Characterization of the Cathode Electrolyte Interface in Lithium Ion Batteries by Desorption Electrospray Ionization Mass Spectrometry.
Liu YM, G Nicolau B, Esbenshade JL, Gewirth AA. Liu YM, et al. Anal Chem. 2016 Jul 19;88(14):7171-7. doi: 10.1021/acs.analchem.6b01292. Epub 2016 Jul 11. Anal Chem. 2016. PMID: 27346184
The solid electrolyte interface (SEI) formed via electrolyte decomposition on the anode of lithium ion batteries is largely responsible for the stable cycling of conventional lithium ion batteries. ...The presence of ethoxy and methoxy end groups indicates both meth …
The solid electrolyte interface (SEI) formed via electrolyte decomposition on the anode of lithium ion batteries is largely responsib …
On the Reaction Pathways and Growth Mechanisms of LiNbO3 Nanocrystals from the Non-Aqueous Solvothermal Alkoxide Route.
Urbain M, Riporto F, Beauquis S, Monnier V, Marty JC, Galez C, Durand C, Chevolot Y, Dantec RL, Mugnier Y. Urbain M, et al. Nanomaterials (Basel). 2021 Jan 9;11(1):154. doi: 10.3390/nano11010154. Nanomaterials (Basel). 2021. PMID: 33435460 Free PMC article.
Phase-pure, highly crystalline sub-50 nm LiNbO(3) nanocrystals were prepared from a non-aqueous solvothermal process for 72 h at 230 C and a commercial precursor solution of mixed lithium niobium ethoxide in its parent alcohol. A systematic variation of the reaction …
Phase-pure, highly crystalline sub-50 nm LiNbO(3) nanocrystals were prepared from a non-aqueous solvothermal process for 72 h at 230 C and a …
A case of anti carbolithiation of alkynes resulting from intramolecular lithium coordination.
Fressigné C, Girard AL, Durandetti M, Maddaluno J. Fressigné C, et al. Chemistry. 2008;14(17):5159-67. doi: 10.1002/chem.200701834. Chemistry. 2008. PMID: 18438769
The results show that the action of one equivalent of n-butyllithium on 1 is sufficient to trigger halogen-lithium exchange and the subsequent heterocyclization step. Interestingly, the reaction stops at the stage of dihydrobenzofuran 6; no spontaneous elimination of li
The results show that the action of one equivalent of n-butyllithium on 1 is sufficient to trigger halogen-lithium exchange and the s …
Synthesis and characterization of d5 -barbarin for use in barbarin-related research.
Kudrimoti S, Machin J, Arojojoye AS, Awuah SG, Eisenberg R, Fenger C, Maylin G, Lehner AF, Tobin T. Kudrimoti S, et al. Drug Test Anal. 2023 Jan;15(1):42-46. doi: 10.1002/dta.3357. Epub 2022 Aug 23. Drug Test Anal. 2023. PMID: 35975356 Free PMC article.
D(5) -barbarin synthesis commenced with production of d(5) -2-oxo-2-phenylacetaldehyde oxime (d(5) -oxime) from d(5) -acetophenone via butylnitrite in an ethoxide/ethanol solution. This d(5) -oxime was then reduced with lithium aluminum hydride (LiAlH(4) ) to produc …
D(5) -barbarin synthesis commenced with production of d(5) -2-oxo-2-phenylacetaldehyde oxime (d(5) -oxime) from d(5) -acetophenone via butyl …
Choosing the best molecular precursor to prepare Li4Ti5O12 by the sol-gel method using (1)H NMR: evidence of [Ti3(OEt)13](-) in solution.
García-Herbosa G, Aparicio M, Mosa J, Cuevas JV, Torroba T. García-Herbosa G, et al. Dalton Trans. 2016 Sep 21;45(35):13888-98. doi: 10.1039/c6dt01949h. Epub 2016 Aug 15. Dalton Trans. 2016. PMID: 27523928
(1)H NMR spectroscopy at 400 MHz in toluene-d8 of evaporated mixtures of lithium ethoxide and titanium(iv) isopropoxide in ethanol, used to prepare the spinel Li4Ti5O12 by the sol-gel method, may help clarify why the atomic ratio 5Li : 5Ti and not 4Li : 5Ti is the r …
(1)H NMR spectroscopy at 400 MHz in toluene-d8 of evaporated mixtures of lithium ethoxide and titanium(iv) isopropoxide in eth …
18 results