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1958 1
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1964 1
1965 2
1966 1
1967 5
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1969 6
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1972 6
1973 3
1974 1
1975 8
1976 7
1977 11
1978 9
1979 7
1980 13
1981 6
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1984 20
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1986 15
1987 16
1988 9
1989 15
1990 14
1991 11
1992 11
1993 12
1994 10
1995 19
1996 16
1997 19
1998 23
1999 31
2000 31
2001 45
2002 51
2003 50
2004 57
2005 54
2006 80
2007 79
2008 77
2009 76
2010 70
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2013 67
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2019 51
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2022 63
2023 57
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1,776 results

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Page 1
Geometrical Isomerism Directed Electrochemical Sensing.
Kottaichamy AR, Begum S, Devendrachari MC, Bhat ZM, Thimmappa R, Nimbegondi Kotresh HM, Vinod CP, Thotiyl MO. Kottaichamy AR, et al. Anal Chem. 2020 Mar 17;92(6):4541-4547. doi: 10.1021/acs.analchem.9b05753. Epub 2020 Feb 27. Anal Chem. 2020. PMID: 32067452
We report the independent role of isomerism of secondary sphere substituents over their nature, a factor often overlooked in molecular electrocatalysis pertaining to electrochemical sensing, by establishing that isomerism redefines the electronic structure at the ca …
We report the independent role of isomerism of secondary sphere substituents over their nature, a factor often overlooked in molecula …
Analysis of geometrical isomers of dietary carotenoids.
Meléndez-Martínez AJ. Meléndez-Martínez AJ. Methods Enzymol. 2022;670:369-398. doi: 10.1016/bs.mie.2021.11.011. Epub 2021 Dec 9. Methods Enzymol. 2022. PMID: 35871841
The presence of double bonds cause carotenoids to be prone to geometrical isomerization. The distinction among geometrical isomers of carotenoids is important as there can be important differences in terms of bioavailability, stability during processing or ev …
The presence of double bonds cause carotenoids to be prone to geometrical isomerization. The distinction among geometrical …
Geometrical isomerization of arachidonic acid during lipid peroxidation interferes with ferroptosis.
Hirata Y, Ferreri C, Yamada Y, Inoue A, Sansone A, Vetica F, Suzuki W, Takano S, Noguchi T, Matsuzawa A, Chatgilialoglu C. Hirata Y, et al. Free Radic Biol Med. 2023 Aug 1;204:374-384. doi: 10.1016/j.freeradbiomed.2023.05.026. Epub 2023 May 29. Free Radic Biol Med. 2023. PMID: 37257700 Free article.
Geometrical mono-trans isomers of arachidonic acid (mtAA) are endogenous products of free radical-induced cis-trans double bond isomerization occurring to natural fatty acids during cell metabolism, including lipid peroxidation (LPO). ...
Geometrical mono-trans isomers of arachidonic acid (mtAA) are endogenous products of free radical-induced cis-trans double bond is …
mer and fac isomerism in tris chelate diimine metal complexes.
Dabb SL, Fletcher NC. Dabb SL, et al. Dalton Trans. 2015 Mar 14;44(10):4406-22. doi: 10.1039/c4dt03535f. Dalton Trans. 2015. PMID: 25600485 Review.
Diimine ligands have long been the workhorse of coordination chemistry, and whilst there are now good strategies to isolate materials where the inherent metal centered chirality is under almost complete control, and systematic methodologies to isolate heteroleptic complexes, the …
Diimine ligands have long been the workhorse of coordination chemistry, and whilst there are now good strategies to isolate materials where …
Enantioselective Synthesis, Enantiomeric Separations and Chiral Recognition.
Tiritan ME, Pinto M, Fernandes C. Tiritan ME, et al. Molecules. 2020 Apr 8;25(7):1713. doi: 10.3390/molecules25071713. Molecules. 2020. PMID: 32276494 Free PMC article.
Chirality is a geometric property associated with the asymmetry of tridimensional features that accompanies our daily life at macroscopic as well as microscopic molecular levels [...]....
Chirality is a geometric property associated with the asymmetry of tridimensional features that accompanies our daily life at macrosc …
Cobalt-Catalyzed Z to E Geometrical Isomerization of 1,3-Dienes.
Wang W, He S, Zhong Y, Chen J, Cai C, Luo Y, Xia Y. Wang W, et al. J Org Chem. 2022 Apr 1;87(7):4712-4723. doi: 10.1021/acs.joc.1c03164. Epub 2022 Mar 11. J Org Chem. 2022. PMID: 35275485
An efficient cobalt-catalyzed geometrical isomerization of 1,3-dienes is described. In the combination of a CoCl(2) precatalyst with an amido-diphosphine-oxazoline ligand, the geometrical isomerization of E/Z mixtures of 1,3-dienes proceed in a stereoc …
An efficient cobalt-catalyzed geometrical isomerization of 1,3-dienes is described. In the combination of a CoCl(2) precatalys …
Influence of the Z/E Isomerism on the Pathway Complexity of a Squaramide-Based Macrocycle.
Orvay F, Cerdá J, Rotger C, Ortí E, Aragó J, Costa A, Soberats B. Orvay F, et al. Small. 2021 Feb;17(7):e2006133. doi: 10.1002/smll.202006133. Epub 2021 Jan 15. Small. 2021. PMID: 33448095
The rising interest on pathway complexity in supramolecular polymerization has prompted the finding of novel monomer designs able to stabilize kinetically trapped species and generate supramolecular polymorphs. In the present work, the exploitation of the Z/E (geometrical) …
The rising interest on pathway complexity in supramolecular polymerization has prompted the finding of novel monomer designs able to stabili …
Geometrical isomerism of monounsaturated fatty acids: thiyl radical catalysis and influence of antioxidant vitamins.
Chatgilialoglu C, Zambonin L, Altieri A, Ferreri C, Mulazzani QG, Landi L. Chatgilialoglu C, et al. Free Radic Biol Med. 2002 Dec 15;33(12):1681-92. doi: 10.1016/s0891-5849(02)01143-7. Free Radic Biol Med. 2002. PMID: 12488136
Thiyl radicals generated either from thiols or disulfides act as the catalyst for the cis-trans isomerization of a variety of monounsaturated fatty acid methyl esters in homogeneous solution. Similar results have also been obtained using alpha-lipoic acid and its reduced f …
Thiyl radicals generated either from thiols or disulfides act as the catalyst for the cis-trans isomerization of a variety of monouns …
Styryl Group, a Friend or Foe in Medicinal Chemistry.
Bhurta D, Bharate SB. Bhurta D, et al. ChemMedChem. 2022 Apr 5;17(7):e202100706. doi: 10.1002/cmdc.202100706. Epub 2022 Mar 2. ChemMedChem. 2022. PMID: 35166041 Review.
However, the Michael acceptor site in the styryl group makes it amenable to the nucleophilic attack by biological nucleophiles and transformation to the toxic metabolites. One of the downsides of styryl compounds is isomerization that impacts the molecular conformation and …
However, the Michael acceptor site in the styryl group makes it amenable to the nucleophilic attack by biological nucleophiles and transform …
Stiff-Stilbene Photoswitches: From Fundamental Studies to Emergent Applications.
Villarón D, Wezenberg SJ. Villarón D, et al. Angew Chem Int Ed Engl. 2020 Aug 3;59(32):13192-13202. doi: 10.1002/anie.202001031. Epub 2020 Jun 2. Angew Chem Int Ed Engl. 2020. PMID: 32222016 Free PMC article. Review.
Stiff-stilbene photoswitches possess a number of advantageous properties including a high quantum yield for photoisomerization and a high thermal stability. Furthermore, they undergo a large geometrical change upon isomerization and their synthesis is straightforwar …
Stiff-stilbene photoswitches possess a number of advantageous properties including a high quantum yield for photoisomerization and a high th …
1,776 results