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diphenates
(2 results)?
catena-Poly[[[aqua-copper(II)]-μ-(biphenyl-2,2'-di-carboxyl-ato)-μ-[N,N'-bis-(pyridin-4-yl)urea]] 1.25-hydrate].
IUCrdata. 2020 May 5;5(Pt 5):x200589. doi: 10.1107/S2414314620005891. eCollection 2020 May.
IUCrdata. 2020.
PMID: 36337154
Free PMC article.
In the title compound, {[Cu(C(14)H(8)O(4))(C(11)H(10)N(4)O)(H(2)O)].1.25H(2)O} (n) , the Cu(II) cations are coordinated in a square-pyramidal fashion by trans carboxyl-ate O-atom donors from two diphenate (dip) ligands, trans pyridyl N-atom donors from two bis-(4-pyrid-yl) …
In the title compound, {[Cu(C(14)H(8)O(4))(C(11)H(10)N(4)O)(H(2)O)].1.25H(2)O} (n) , the Cu(II) cations are coordinated in a square-pyramida …
Zero-, mono- and diperiodic uranyl ion complexes with the diphenate dianion: influences of transition metal ion coordination and differential U(VI) chelation.
Thuéry P , Atoini Y , Harrowfield J .
Thuéry P , et al.
Dalton Trans. 2020 Jan 21;49(3):817-828. doi: 10.1039/c9dt04126e.
Dalton Trans. 2020.
PMID: 31854436
Diphenic acid (H2dip) has been used to synthesize nine homo- or heterometallic uranyl ion complexes under solvo-hydrothermal conditions. The diphenate ligand dip2- adopts different coordination modes, mixtures of kappa2-O,O'-chelation by individual carboxylate groups, chel …
Diphenic acid (H2dip) has been used to synthesize nine homo- or heterometallic uranyl ion complexes under solvo-hydrothermal conditions. The …
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Valence tautomerism and metal-mediated catechol oxidation for complexes of copper prepared with 9,10-phenanthrenequinone.
Speier G, Tyeklár Z, Tóth P, Speier E, Tisza S, Rockenbauer A, Whalen AM, Alkire N, Pierpont CG.
Speier G, et al.
Inorg Chem. 2001 Oct 22;40(22):5653-9. doi: 10.1021/ic010373g.
Inorg Chem. 2001.
PMID: 11599966
Structural characterization on products obtained with tmeda show that dioxygen insertion across the C-C bond within the chelate ring leads to dimeric products with adjacent Cu(II) ions bridged by diphenate ligands. The addition of O(2) to Cu(tmeda)(PhenCat) in acetonitrile …
Structural characterization on products obtained with tmeda show that dioxygen insertion across the C-C bond within the chelate ring leads t …
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