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2,119 results

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Page 1
Cyclopentadienyl ring activation in organometallic chemistry and catalysis.
VanderWeide A, Prokopchuk DE. VanderWeide A, et al. Nat Rev Chem. 2023 Aug;7(8):561-572. doi: 10.1038/s41570-023-00501-1. Epub 2023 May 31. Nat Rev Chem. 2023. PMID: 37258685 Review.
The cyclopentadienyl (Cp) ligand is a cornerstone of modern organometallic chemistry. ...
The cyclopentadienyl (Cp) ligand is a cornerstone of modern organometallic chemistry. ...
Cyclopentadienyl Complexes of the Alkaline Earths in Light of the Periodic Trends.
Baguli S, Mondal S, Mandal C, Goswami S, Mukherjee D. Baguli S, et al. Chem Asian J. 2022 Jan 3;17(1):e202100962. doi: 10.1002/asia.202100962. Epub 2021 Nov 25. Chem Asian J. 2022. PMID: 34825506 Review.
The electron-rich cyclopentadienyl and the analogous indenyl and fluorenyl ligands (collectively denoted here as Cp') have been impactful in stabilizing electron-deficient metal centers including the highly electropositive alkaline earths. ...
The electron-rich cyclopentadienyl and the analogous indenyl and fluorenyl ligands (collectively denoted here as Cp') have been impac …
{Cyclopentadienyl/Fluorenyl}-Group 4 ansa-Metallocene Catalysts for Production of Tailor-Made Polyolefins.
Kirillov E, Carpentier JF. Kirillov E, et al. Chem Rec. 2021 Feb;21(2):357-375. doi: 10.1002/tcr.202000142. Epub 2020 Dec 17. Chem Rec. 2021. PMID: 33332719 Free article. Review.
This personal account summarizes our continuing endeavors to advance the family of industry-relevant stereoselective propylene polymerization catalysts based on C(1) -symmetric group 4 ansa-metallocenes incorporating multi-substituted fluorenyl-cyclopentadienyl {Cp/Flu} li …
This personal account summarizes our continuing endeavors to advance the family of industry-relevant stereoselective propylene polymerizatio …
Cobalt Cyclopentadienyl-Phosphine Dinitrogen Complexes.
Wang GX, Yan X, Yin J, Yin ZB, Wei J, Xi Z. Wang GX, et al. Chemistry. 2022 Dec 1;28(67):e202202803. doi: 10.1002/chem.202202803. Epub 2022 Nov 14. Chemistry. 2022. PMID: 36259370
By applying the potassium salts of cyclopentadienyl-phosphine ligands LK to CoCl(2) , the corresponding cobalt chlorides (1, LCo(II) Cl) were prepared. ...Further reduction of complex 2 b led to cleavage of a P-C bond in the cyclopentadienyl-phosphine ligand to prov …
By applying the potassium salts of cyclopentadienyl-phosphine ligands LK to CoCl(2) , the corresponding cobalt chlorides (1, LCo(II) …
Chiral Cyclopentadienyl Ligands: Design, Syntheses, and Applications in Asymmetric Catalysis.
Mas-Roselló J, Herraiz AG, Audic B, Laverny A, Cramer N. Mas-Roselló J, et al. Angew Chem Int Ed Engl. 2021 Jun 7;60(24):13198-13224. doi: 10.1002/anie.202008166. Epub 2020 Oct 30. Angew Chem Int Ed Engl. 2021. PMID: 32672405 Review.
Herein we offer a historical overview on the development of chiral derivatives of the ubiquitous cyclopentadienyl ligand (Cp(X) ), and detail their successful application in a broad range of metal-catalyzed transformations. ...
Herein we offer a historical overview on the development of chiral derivatives of the ubiquitous cyclopentadienyl ligand (Cp(X) ), an …
High-Efficiency Mono-Cyclopentadienyl Titanium and Rare-Earth Metal Catalysts for the Production of Syndiotactic Polystyrene.
Wen B, Hu H, Kang D, Sang C, Mao G, Xin S. Wen B, et al. Molecules. 2023 Sep 25;28(19):6792. doi: 10.3390/molecules28196792. Molecules. 2023. PMID: 37836635 Free PMC article. Review.
In this context, the use of mono-cyclopentadienyl titanocene (mono-Cp'Ti) catalysts and mono-cyclopentadienyl rare-earth metal (mono-Cp'RE) metallocene catalysts for the syndiospecific polymerization of styrene is discussed. The effects of the mono-cyclopentadien
In this context, the use of mono-cyclopentadienyl titanocene (mono-Cp'Ti) catalysts and mono-cyclopentadienyl rare-earth metal …
(eta5-cyclopentadienyl)(N,N-dimethyldithiocarbamato-kappa2S,S')[eta4-tetrakis(trifluoromethyl)cyclobutadienyl]molybdenum(IV).
Davidson JL, Jarvie A, Muir KW. Davidson JL, et al. Acta Crystallogr C. 2005 Apr;61(Pt 4):m209-10. doi: 10.1107/S0108270105006086. Epub 2005 Mar 25. Acta Crystallogr C. 2005. PMID: 15805629
The title complex, [Mo(C8F12)(C5H5)(C3H6NS2)], contains both a eta4-C4(CF3)4 cyclobutadienyl ligand with approximate C4v local symmetry and a eta5-C5H5 cyclopentadienyl ring. The centroids of the rings and the S atoms of a chelating dithiocarbamate ligand define the pseudo …
The title complex, [Mo(C8F12)(C5H5)(C3H6NS2)], contains both a eta4-C4(CF3)4 cyclobutadienyl ligand with approximate C4v local symmetry and …
Evoking Ferroptosis by Synergistic Enhancement of a Cyclopentadienyl Iridium-Betulin Immune Agonist.
Lv M, Zheng Y, Wu J, Shen Z, Guo B, Hu G, Huang Y, Zhao J, Qian Y, Su Z, Wu C, Xue X, Liu HK, Mao ZW. Lv M, et al. Angew Chem Int Ed Engl. 2023 Nov 27;62(48):e202312897. doi: 10.1002/anie.202312897. Epub 2023 Oct 27. Angew Chem Int Ed Engl. 2023. PMID: 37830171
Ferroptosis is a form of programmed cell death driven by iron-dependent lipid peroxidation (LPO) with the potential for antitumor immunity activation. In this study, a nonferrous cyclopentadienyl metal-based ferroptosis inducer [Ir(Cp*)(Bet)Cl]Cl (Ir-Bet) was developed by …
Ferroptosis is a form of programmed cell death driven by iron-dependent lipid peroxidation (LPO) with the potential for antitumor immunity a …
Cyclopentadienyl-Based Anticancer Drugs: Improvement of Cytotoxic Activity through Functionalisation of the pi Ligand.
Absolonová M, Melounková L, Vinklárek J, Honzíček J, Dostál L, Mrózek O. Absolonová M, et al. ChemMedChem. 2021 Jun 7;16(11):1804-1812. doi: 10.1002/cmdc.202100060. Epub 2021 Mar 24. ChemMedChem. 2021. PMID: 33635596
Compounds of the type [(eta(5) -Cp')Mo(CO)(2) ((N,N) L)][BF(4) ], where Cp is cyclopentadienyl and (N,N) L is a bidentate ligand, are well known for their strong anticancer activity. ...These results are of crucial importance for the future design of highly active cytotoxi …
Compounds of the type [(eta(5) -Cp')Mo(CO)(2) ((N,N) L)][BF(4) ], where Cp is cyclopentadienyl and (N,N) L is a bidentate ligand, are …
2,119 results