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Synthesis and chemistry of 2,3-dioxabicyclo[2.2.2]octane-5,6-diols.
Valente P, Avery TD, Taylor DK, Tiekink ER. Valente P, et al. J Org Chem. 2009 Jan 2;74(1):274-82. doi: 10.1021/jo8020506. J Org Chem. 2009. PMID: 19035821
1,4-Disubstituted 2,3-dioxabicyclo[2.2.2]oct-5-enes were dihydroxylated with osmium tetroxide to yield diols anti to the peroxide linkage in a highly selective manner. Reduction of the peroxide bond furnished cyclohexane-1,2,3,4-tetraols with toxocarol …
1,4-Disubstituted 2,3-dioxabicyclo[2.2.2]oct-5-enes were dihydroxylated with osmium tetroxide to yield diols anti to the peroxide linkage in …
Polyol monoterpenes isolated from Chenopodium ambrosioides.
Hou SQ, Li YH, Huang XZ, Li R, Lu H, Tian K, Ruan RS, Li YK. Hou SQ, et al. Nat Prod Res. 2017 Nov;31(21):2467-2472. doi: 10.1080/14786419.2017.1314278. Epub 2017 Apr 12. Nat Prod Res. 2017. PMID: 28399680
Phytochemical study on the 95% ethyl alcohol extract of stems of Chenopodium ambrosioides resulted in the isolation of two new polyol monoterpenes, 4-hydroxy-4(alpha or beta)-isopropyl-2-methyl-2-cyclohexen-1-one (1) and 1-methyl-4beta- isopropyl-1-cyclohexene-4alpha,5alpha,6alph …
Phytochemical study on the 95% ethyl alcohol extract of stems of Chenopodium ambrosioides resulted in the isolation of two new polyol monote …
Cocrystallization and configurations of myo-inositol-1,2-L-camphor acetals in two crystal structures.
Gainsford GJ, Baars SM, Falshaw A. Gainsford GJ, et al. Acta Crystallogr C. 2007 Mar;63(Pt 3):o169-72. doi: 10.1107/S0108270107004416. Epub 2007 Feb 17. Acta Crystallogr C. 2007. PMID: 17339723
The inositol rings in (1S,2R,3R,4S,5S,6R,7S,8S,11S)-myo-inositol-1,2-camphor acetal {systematic name: (1R,2S,3S,4R,5S,6R)-5,6-[(1S,2S,4S)-1,7,7-trimethylbicyclo[2.2.1]heptane-2,2-diyldioxy]cyclohexane-1,2,3,4-tetrol}, C(16)H(26)O(6), and …
The inositol rings in (1S,2R,3R,4S,5S,6R,7S,8S,11S)-myo-inositol-1,2-camphor acetal {systematic name: (1R,2S,3S,4R,5S,6R)-5,6-[(1S,2S,4S)-1, …