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Photochemical generation and reversible cycloaromatization of a nine-membered ring cyclic enediyne.
Pandithavidana DR, Poloukhtine A, Popik VV. Pandithavidana DR, et al. J Am Chem Soc. 2009 Jan 14;131(1):351-6. doi: 10.1021/ja8077076. J Am Chem Soc. 2009. PMID: 19053819
The latter rapidly equilibrates with the corresponding 1,4-didehydronaphthalene diradical and then undergoes rate-limiting hydrogen abstraction to produce the ultimate product of the Bergman cyclization, benz[f]indanol....
The latter rapidly equilibrates with the corresponding 1,4-didehydronaphthalene diradical and then undergoes rate-limiting hydrogen abstract …
Design and synthesis of side-chain conformationally restricted phenylalanines and their use for structure-activity studies on tachykinin NK-1 receptor.
Josien H, Lavielle S, Brunissen A, Saffroy M, Torrens Y, Beaujouan JC, Glowinski J, Chassaing G. Josien H, et al. J Med Chem. 1994 May 27;37(11):1586-601. doi: 10.1021/jm00037a009. J Med Chem. 1994. PMID: 7515443
., L-tetrahydroisoquinoleic acid, L-diphenylalanine, L-9-fluorenylglycine (Flg), 2-indanylglycine, the diastereomers of L-1-indanylglycine (Ing) and L-1-benz[f]indanylglycine (Bfi), and the Z and E isomers of dehydrophenylalanine (delta ZPhe, delta EPhe). ...
., L-tetrahydroisoquinoleic acid, L-diphenylalanine, L-9-fluorenylglycine (Flg), 2-indanylglycine, the diastereomers of L-1-indanylglycine ( …