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Photoactive Metal-to-Ligand Charge Transfer Excited States in 3d6 Complexes with Cr0, MnI, FeII, and CoIII.
Sinha N, Wenger OS. Sinha N, et al. J Am Chem Soc. 2023 Mar 8;145(9):4903-4920. doi: 10.1021/jacs.2c13432. Epub 2023 Feb 21. J Am Chem Soc. 2023. PMID: 36808978 Free PMC article. Review.
Many coordination complexes and organometallic compounds with the 4d(6) and 5d(6) valence electron configurations have outstanding photophysical and photochemical properties, which stem from metal-to-ligand charge transfer (MLCT) excited states. ...
Many coordination complexes and organometallic compounds with the 4d(6) and 5d(6) valence electron configurations have outstanding ph …
Electrochemiluminescence of a First-Row d6 Transition Metal Complex.
Doeven EH, Connell TU, Sinha N, Wenger OS, Francis PS. Doeven EH, et al. Angew Chem Int Ed Engl. 2024 Mar 22:e202319047. doi: 10.1002/anie.202319047. Online ahead of print. Angew Chem Int Ed Engl. 2024. PMID: 38519420
We report the electrochemiluminescence (ECL) of a 3d(6) Cr(0) complex ([Cr(L(Mes))(3)]; lambda(em)=735 nm) with comparable photophysical properties to those of ECL-active complexes of 4d(6) or 5d(6) precious metal ions. The electrochemical potentials of [Cr(L(Mes))(3)] are …
We report the electrochemiluminescence (ECL) of a 3d(6) Cr(0) complex ([Cr(L(Mes))(3)]; lambda(em)=735 nm) with comparable photophysical pro …
Long-Lived, Strongly Emissive, and Highly Reducing Excited States in Mo(0) Complexes with Chelating Isocyanides.
Herr P, Glaser F, Büldt LA, Larsen CB, Wenger OS. Herr P, et al. J Am Chem Soc. 2019 Sep 11;141(36):14394-14402. doi: 10.1021/jacs.9b07373. Epub 2019 Aug 29. J Am Chem Soc. 2019. PMID: 31464429
Our comprehensive optical spectroscopic and photochemical study shows that Mo(0) complexes with diisocyanide chelate ligands constitute a new family of luminophores and photosensitizers, which is complementary to precious metal-based 4d(6) and 5d(6) complexes and represent …
Our comprehensive optical spectroscopic and photochemical study shows that Mo(0) complexes with diisocyanide chelate ligands constitute a ne …
A 6.5-year follow-up of 14 patients who underwent ProDisc total disc arthroplasty for combined long-standing degenerative lumbar disc disease and recent disc herniation.
Markwalder TM, Wenger M, Marbacher S. Markwalder TM, et al. J Clin Neurosci. 2011 Dec;18(12):1677-81. doi: 10.1016/j.jocn.2011.04.024. Epub 2011 Nov 17. J Clin Neurosci. 2011. PMID: 22099076
At an average of 6.5 years after surgery, all were reassessed using the SWISSDISC-questionnaire, which involves the EuroQol-5D and North American Spine Society evaluations (general health, low-back and lower limb status), and a telephone call. ...
At an average of 6.5 years after surgery, all were reassessed using the SWISSDISC-questionnaire, which involves the EuroQol-5D and No …
Preparation of benzyne complexes of group 10 metals by intramolecular suzuki coupling of ortho-metalated phenylboronic esters: molecular structure of the first benzyne-palladium(0) complex.
Retbøll M, Edwards AJ, Rae AD, Willis AC, Bennett MA, Wenger E. Retbøll M, et al. J Am Chem Soc. 2002 Jul 17;124(28):8348-60. doi: 10.1021/ja0264091. J Am Chem Soc. 2002. PMID: 12105916
Complex 3d also reacts with KO(t)Bu, but in this case disproportionation of the initially formed eta(2)-C(6)H(4) complex (5d) leads to a 1:1 mixture of a novel dinuclear palladium(I) complex, [(dcpe)Pd(mu(2)-C(6)H(4))Pd(dcpe)] (6), and a 2,2'-biphenyldiyl complex, [Pd(2,2' …
Complex 3d also reacts with KO(t)Bu, but in this case disproportionation of the initially formed eta(2)-C(6)H(4) complex (5d) leads t …